| Title | : | Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks |
| Author | : | Basudev Sahoo |
| Language | : | en |
| Rating | : | 4.90 out of 5 stars |
| Type | : | PDF, ePub, Kindle |
| Uploaded | : | Apr 03, 2021 |
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Visible-light photocatalyzed oxidative decarboxylation of oxamic acids: a green route to urethanes and ureas chem commun (camb) 2018 aug 16;54(67):9337-9340.
Visible-light photocatalysis has evolved over the last decade into a widely used method in organic synthesis. Photocatalytic variants have been reported for many important transformations, such as cross-coupling reactions, α-amino functionalizations, cycloadditions, atra reactions, or fluorinations.
Visible light photocatalysis has evolved over the last decade into a widely used method in organic synthesis. For many important transformations, such as cross-coupling reactions, alpha-amino.
Visible light‐mediated organic‐transformations has emerged as an efficient and environmentally compatible synthetic strategy in modern organic synthesis. Due to its simplicity and mildness, in recent years, there is an increase of interest in the photoinduced c−se bond functionalization.
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Visible light emerging from the source of sun promotes chemical transformations through single-electron mechanism. Basically using visible light as energy source and in the presence of catalytic amount of metal photosensitizers or organocatalysts, the chemical reactions are carried out, and this process is termed as visible-light photocatalysis.
Thiolated ligands on qds by utilizing the photocatalytic activity of qds upon absorbing visible light. We show that using visible light leads to better ligand cross-linking by avoiding the problem of ligand dissociation that occurs upon uv light exposure.
A straightforward synthetic strategy to construct biologically relevant phenanthridinones and quinolinones was developed via visible-light-promoted direct oxidative c–h amidation. In this photocatalytic system, amidyl radicals can be generated by homolysis of the n–h bond of simple amide precursors via single-electron transfer under blue led illumination, which leads to oxidative intramolecular c–h amidation.
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Visible‐light‐photocatalyzed methods employed in synthetic transformations present attractive properties such as environmentally friendly, safety, availability and excellent functional group tolerance.
Visible light photoredox catalysis has emerged as a powerful tool in organic synthesis, building upon the foundation set by early pioneers in the areas of radical chemistry and photochemistry. Photoredox chemistry allows one to forge new bonds via open shell pathways and facilitates the rapid assembly of complex products en route to new areas.
Apr 8, 2017 recently, visible-light photocatalysis has offered a technically attractive and energy-saving platform for aerobic oxidation.
Jul 21, 2015 the photocatalytic nanomaterial can be used to treat water using visible light.
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Jul 10, 2014 further showed that nitrogen-doped tio2 exhibit a substantial enhancement in visible light assisted photocatalytic degradation of methylene.
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Edited by rising stars in the scientific community, the text focuses solely on visible light photocatalysis in the context of organic chemistry. This primarily entails photoinduced electron transfer and energy transfer chemistry sensitized by polypyridyl complexes, yet also includes the use of organic dyes and heterogeneous catalysts.
Visible-light photocatalyzed deoxygenation of n-heterocyclic n-oxides a scalable and operationally simple method is described that allows for the chemoselective deoxygenation of a wide range of n-heterocyclic n-oxides (a total of 36 examples).
Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful uv light in photo-mediated reactions.
May 12, 2011 facilitated by atomic force microscopy, this study analyzes the visible-light driven photocatalyst-mediated damage of escherichia coli.
Visible‐light photocatalysis has evolved over the last decade into a widely used method in organic synthesis. Photocatalytic variants have been reported for many important transformations, such as cross‐coupling reactions, α‐amino functionalizations, cycloadditions, atra reactions, or fluorinations.
Oct 4, 2016 the band gap of tio2 is narrowed as a few crystal lattice oxygen atoms are substituted by nitrogen, enabling the tio2 to have photocatalytic.
Visible-light photoredox catalysis offers a distinct activation mode complementary to thermal transition metal catalyzed reactions. The vast majority of photoredox processes capitalizes on precious.
Visible light-mediated photocatalysis, which relies on the ability of photocatalysts to absorb low-energy visible light and engage in single-electron transfer (set) or energy transfer (et) processes with organic substrates, has emerged as one of the fastest growing fields in organic synthesis. This catalytic platform enables a highly selective approach to promote radical-based organic.
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